硅酸锆含量对硅基陶瓷型芯性能的影响

doi:10.12066/j.issn.1007-2861.1994

上海大学学报(自然科学版) ›› 2019, Vol. 25 ›› Issue (4): 453-461.doi: 10.12066/j.issn.1007-2861.1994

硅酸锆含量对硅基陶瓷型芯性能的影响

赵登科, 玄伟东, 刘利俊, 兰健, 任忠鸣()

上海大学省部共建高品质特殊钢冶金与制备国家重点实验室, 上海 200444

收稿日期:2017-07-01 出版日期:2019-08-30 发布日期:2019-09-04
通讯作者: 任忠鸣 E-mail:zmren@shu.edu.cn
基金资助:
国家自然科学基金资助项目(51604172);国家自然科学基金资助项目(U1560202)

Effect of zircon content on the properties of silica based ceramic core

Dengke ZHAO, Weidong XUAN, Lijun LIU, Jian LAN, Zhongming REN()

State Key Laboratory of Advanced Special Steel, Shanghai University, Shanghai 200444, China

Received:2017-07-01 Online:2019-08-30 Published:2019-09-04
Contact: Zhongming REN E-mail:zmren@shu.edu.cn

摘要/Abstract

摘要：

以石英玻璃粉为基体、硅酸锆为添加剂、陶瓷铸造蜡为增塑剂, 利用热压注法制备硅基陶瓷型芯, 烧结成型, 并测试了烧结后型芯性能的变化, 研究了硅酸锆添加量对硅基陶瓷型芯性能的影响. 结果表明: 硅酸锆添加量对型芯析晶并无明显影响. 由于硅酸锆熔点高、性能稳定, 不与二氧化硅发生反应, 能够降低石英玻璃的黏性流动和型芯的烧结程度, 导致硅酸锆添加量越多, 样品的收缩率、室温强度越低, 显气孔率越大. 少量硅酸锆分布于石英玻璃基体中, 起强化基体的骨架作用, 能够提高型芯的高温强度. 当硅酸锆含量较高时, 石英玻璃含量降低, 石英玻璃析晶产生的方石英含量降低, 导致型芯的高温强度下降. 型芯的高温挠度随硅酸锆含量的增加而降低, 这是因为硅酸锆在高温下能够降低石英玻璃的黏性流动.

关键词: 陶瓷型芯, 硅酸锆添加量, 型芯析晶, 黏性流动

Abstract:

The ceramic core was prepared using the hot injection method, where quartz glass powders were used as original materials, zircon as additive, and the ceramic casting wax as the plasticizer. The purpose is to test the changes in the properties of cores and the effect of zircon content on the properties of silica-based ceramic core. It was learned that the zircon additive has no obvious effect on core crystallization. Zircon, which has high melting point and stability, did not react with silica and could reduce the viscous flow of quartz glass and the degree of sintering of the core. As a result, the more zircon was added, the lower the shrinkage and room temperature strength were, and the greater the porosity was. A small amount of zircon, which was distributed in the quartz glass matrix, contributed to strengthening the matrix and also improved the high temperature strength of the core. When the content of zirconium silicate was high, the content of quartz glass decreased, and the content of quartzite which resulted from crystallization of quartz glass decreased as well, and this resulted in the lowering of high temperature strength. The high temperature deflection of the core decreased with the increase of the zircon content because zircon could reduce the viscous flow of quartz glass at high temperature.

Key words: ceramic core, zircon addition, crystallization of core, viscous flow

中图分类号:

TQ174

赵登科, 玄伟东, 刘利俊, 兰健, 任忠鸣. 硅酸锆含量对硅基陶瓷型芯性能的影响[J]. 上海大学学报(自然科学版), 2019, 25(4): 453-461.

Dengke ZHAO, Weidong XUAN, Lijun LIU, Jian LAN, Zhongming REN. Effect of zircon content on the properties of silica based ceramic core[J]. Journal of Shanghai University（Natural Science Edition）, 2019, 25(4): 453-461.

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参考文献 21

[1]	Wang F, Li F, Zhou L H . Review of ceramic core for superalloy hollow blade[J]. Aeronautical Manufacturing Technology, 2009(19):60-64.
[2]	刘大响, 金捷, 彭友梅 , 等. 大型飞机发动机的发展现状和关键技术分析[J]. 航空动力学报, 2008,23(6):976-980.
[3]	唐世艳, 樊自田, 刘鑫旺, 等 . 基于 Al 粉成孔作用制备多孔氧化铝陶瓷型芯[J]. 华中科技大学学报(自然科学版), 2017,45(4):34-38.
[4]	王毅强, 成来飞, 张立同 . 相组成与微结构对硅基陶瓷型芯性能的影响[J]. 航空制造技术, 2007(3):92-94.
[5]	王荣峰, 刘志义, 林茂 , 等. 不同矿化剂对铝基陶瓷型芯性能的影响[J]. 材料导报, 2012,26(20):115-118.
[6]	方军民, 余建波, 杨治刚 , 等. 多孔镁基陶瓷型芯的性能研究[J]. 铸造, 2013,62(7):628-632.
[7]	赵效忠 . 陶瓷型芯的制备与使用 [M]. 北京: 科学出版社, 2013: 242-243.
[8]	Kaiser R A, Lobert M, Telle R . Thermal stability of zircon (ZrSiO$_4$)[J]. Journal of the Ceramic Society, 2008,28(11):2199-2211.
[9]	Wang L Y, Hon M H . The effects of zircon addition on the crystallization of fused silica: a kinetic study[J]. Nippon Seramikkusu Cyokai Gakujutsu Ronbunshi, 2010,102(1186):517-521.
[10]	Wilson P J, Blackburn S, Greenwood R W , et al. The role of zircon particle size distribution surface area and contamination on the properties of silica-zircon ceramic materials[J]. Journal of the European Ceramic Society, 2011,31(9):1849-1855.
[11]	Curtis C E, Sowman H G . Investigation of the thermal dissociation, reassociation and synjournal of zircon[J]. Journal of the American Ceramic Society Society, 2010,36(6):190-198.
[12]	徐子烨, 玄伟东, 张金垚 , 等. 烧结温度和粒度分布对多孔氧化硅陶瓷型芯材料性能的影响[J]. 上海大学学报(自然科学版), 2015,21(1):28-37. doi: 10.3969/j.issn.1007-2861.2014.04.016
[13]	潘继勇, 刘孝福, 何立明 . 硅基陶瓷型芯的研究进展[J]. 铸造, 2012,61(2):174-178.
[14]	赵冉, 孙洪巍, 刘慧娟 . 复合烧结助剂对Al$_{2}$O$_{3}$-ZrO$_{2}$陶瓷相对密度的影响[J]. 硅酸盐通报, 2011,30(2):271-277.
[15]	Hoskin P W O, Schaltegger U . The composition of zircon and igneous and metamorphic petrogenesis[J]. Reviews in Mineralogy and Geochemistry, 2003,53(1):27-62.
[16]	Lee J H . Ternary phase analysis of interfacial silicates grown in HfO$_x$/Si and Hf/SiO$_2$/Si systems[J]. Thin Solid Films, 2005,472(1):317-322.
[17]	郝小勇, 范盘华 . 硅酸锆中放射性元素分析[J]. 佛山陶瓷, 2007,17(9):8-10.
[18]	唐亚俊, 王景周 . 添加 30wt${\%}$ ZrSiO$_{4}$ 硅基陶瓷型芯高温特性的研究[J]. 铸造技术, 1992(1):11-15.
[19]	贺靠团 . 定向硅基陶芯生产使用中的重点问题[J]. 材料工程, 1994(2):44-45.
[20]	Kazemi A, Faghihi-Sani M A, Nayyeri M J , et al. Effect of zircon content on chemical and mechanical behavior of silica-based ceramic cores[J]. Ceramics International, 2014,40(1):1093-1098.
[21]	滕瑞, 李金国, 刘纪德 , 等. 终烧温度对陶瓷型芯性能的作用[J]. 沈阳工业大学学报, 2014,36(1):23-27.

硅酸锆含量对硅基陶瓷型芯性能的影响

Effect of zircon content on the properties of silica based ceramic core

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