含氟砌块的分子设计合成及其在合成含氟杂环化合物中的应用

doi:10.3969/j.issn.1007-2861.2011.04.013

上海大学学报(自然科学版) ›› 2011, Vol. 17 ›› Issue (4): 458-470.doi: 10.3969/j.issn.1007-2861.2011.04.013

含氟砌块的分子设计合成及其在合成含氟杂环化合物中的应用

蒋海珍1，宋力平1,2，罗会华1，易海1，朱仕正2，郝健1,2

1.上海大学理学院，上海 200444; 2.中国科学院有机氟化学重点实验室，上海 200032

收稿日期:2011-06-30 出版日期:2011-08-30 发布日期:2011-08-30
通讯作者: 郝健（1964~），男，教授，博士生导师，博士，研究方向为有机氟化学、功能材料等. E-mail：jhao@staff.shu.edu.cn E-mail:E-mail：jhao@staff.shu.edu.cn
基金资助:
国家自然科学基金资助项目(20772079,21072127,21032006,21072128)；上海市科委基金资助项目 (08JC1409900, 10JC1405600)

Design and Synthesis of Fluorine-Containing Building Blocks and Application to Synthesis of Fluorinated Heterocycles

JIANG Hai-zhen1,SONG Li-ping1,2,LUO Hui-hua1,YI Hai1,ZHU Shi-zheng2,HAO Jian1,2

1. College of Sciences, Shanghai University, Shanghai 200444, China; 2. Key Laboratory of Organofluorine Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Received:2011-06-30 Online:2011-08-30 Published:2011-08-30

摘要/Abstract

摘要： 由于氟原子赋予的特殊性能,含氟杂环化合物在医药、农药及特种功能材料等研究领域受到广泛关注.综述近年来本研究团队常用的一些新颖含氟砌块如含氟酮酸酯、含氟亚胺酰卤等的设计合成及其在含氟杂环化合物合成中的应用进展.

关键词: 含氟砌块, 含氟杂环化合物, 酮酸酯, 亚胺酰卤

Abstract: Fluorinated heterocycles have attracted substantial research attention in the fields of medicine, pesticide and special-function materials, which have special properties caused by fluorine atoms. This review highlights the recent development on the synthesis of novel fluorine-containing building blocks, such as fluorine-containing keto esters and fluorine-containing imidoyl halides, and on their applications to the preparation of fluorinated heterocycles.

Key words: fluorinated heterocycle, fluorine-containing building block, imidoyl halide, keto ester

中图分类号:

O 626

蒋海珍1，宋力平1,2，罗会华1，易海1，朱仕正2，郝健1,2. 含氟砌块的分子设计合成及其在合成含氟杂环化合物中的应用[J]. 上海大学学报(自然科学版), 2011, 17(4): 458-470.

JIANG Hai-zhen1,SONG Li-ping1,2,LUO Hui-hua1,YI Hai1,ZHU Shi-zheng2,HAO Jian1,2. Design and Synthesis of Fluorine-Containing Building Blocks and Application to Synthesis of Fluorinated Heterocycles[J]. Journal of Shanghai University（Natural Science Edition）, 2011, 17(4): 458-470.

含氟砌块的分子设计合成及其在合成含氟杂环化合物中的应用

Design and Synthesis of Fluorine-Containing Building Blocks and Application to Synthesis of Fluorinated Heterocycles

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